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ChemInform Abstract: Enantioselective Diels-Alder Approach to Angucyclinones from (S)-2-(p- Tolylsulfinyl)-1,4-naphthoquinone and Substituted Racemic Vinylcyclohexenes.

✍ Scribed by C. CARRENO; A. URBANO; J. FISCHER

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Enantioselective Diels-Alder Approach to Angucyclinones from (S)-2-(p-Tolylsulfinyl)-1,4-naphthoquinone and Substituted Racemic Vinylcyclohexenes.

-The title reaction produces compounds such as (III) with the generation of three stereogenic centers in a one-pot domino reaction with kinetic resolution of the racemic diene.

-(CARRENO, C.;

📜 SIMILAR VOLUMES

Enantioselective Diels-Alder Approach to
Enantioselective Diels-Alder Approach to C-3-Oxygenated Angucyclinones from (SS)-2-(p-Tolylsulfinyl)-1,4-naphthoquinone
✍ M. Carmen Carreño; Antonio Urbano; Claudio Di Vitta 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB

Chiral racemic vinylcyclohexenes 2, bearing oxygenated substituents and/or a methyl group at the C-5 position of the cyclohexene ring, were submitted to Diels-Alder reactions with enantiomerically pure (SS)-(2-p-tolylsulfinyl)-1,4-naphthoquinone [(+)-1]. The domino cycloaddition/pyrolytic sulfoxide