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Enantioselective deprotonation by chiral lithium amide bases: asymmetric synthesis of trimethylsilyl enol ethers from 4-alkylcyclohexanones

✍ Scribed by Shirai, Ryuichi.; Tanaka, Masahide.; Koga, Kenji.


Book ID
120582874
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
347 KB
Volume
108
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Enantioselective De
✍ K. AOKI; K. KOGA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 2 views

Enantioselective Deprotonation of 4-tert-Butylcyclohexanone by Fluorine-Containing Chiral Lithium Amides Derived from Ξ±-Phenethylamine. -The conversion of (I) to the corresponding chiral silyl enol ether using Ξ±-phenethylamine derived chiral lithium amides is investigated. The highest enantioselecti