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ChemInform Abstract: Enantioselective Deprotonation of 4-tert-Butylcyclohexanone by Conformationally Constrained Chiral Lithium Amide Bases.

✍ Scribed by Varinder K. Aggarwal; Paul S. Humphries; Ashley Fenwick

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200005035

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## Stereochemistry of Enantioselective Deprotonation of 4-Substituted Cyclohexanones by Chiral Bidentate Lithium Amides. -Enantioselective deprotonation of 4-substituted cyclohexanones using chiral lithium amide bases such as (I) in the presence of excess trimethylsilyl chloride results in format