Deracemization of axially dissymmetric c
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Lucette Duhamel; Alain Ravard; Jean-Christophe Plaquevent
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Article
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1990
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Elsevier Science
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English
β 148 KB
New findings about deracemlzatlon of unsaturated carboxylic acids 1 by enantloselectlve dehydrohalogenatlon of prochlral species 2 by chiral lithium amides leading to axially dlssymmetric compounds wlth 80% e.e. are reported. The role of the structure of the prochiral hydrochlorinated intermediate i