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Enantioselective dehydrohalogenation via asymmetric deprotonation by chiral lithium amides: Deracemization of a compound bearing a chiral axis

✍ Scribed by Lucette Duhamel; Alain Ravard; Jean-Christophe Plaquevent; Daniel Davoust


Book ID
104228062
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
254 KB
Volume
28
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Deracemization of axially dissymmetric c
✍ Lucette Duhamel; Alain Ravard; Jean-Christophe Plaquevent πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 148 KB

New findings about deracemlzatlon of unsaturated carboxylic acids 1 by enantloselectlve dehydrohalogenatlon of prochlral species 2 by chiral lithium amides leading to axially dlssymmetric compounds wlth 80% e.e. are reported. The role of the structure of the prochiral hydrochlorinated intermediate i