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Enantioselective cyanation of aldehydes catalyzed by bifunctional salen–aluminum complex

✍ Scribed by Chengwei Lv; Cheng-Xia Miao; Daqian Xu; Shoufeng Wang; Chungu Xia; Wei Sun


Book ID
116343943
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
291 KB
Volume
27
Category
Article
ISSN
1566-7367

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Asymmetric Alkynylation of Aldehydes Cat
✍ Chun SHEN; Lei CHEN; Jie TANG; Minghua XU 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB 👁 1 views

## Abstract The asymmetric alkynylation of aldehydes catalyzed by bifunctional Zn(salen) catalyst was realized. With a Kozlowski salen ligand (7e) bearing secondary basic 1‐piperidinylmethyl groups at C‐3 and C‐3′, the enhanced catalytic reactivity and stereoselectivity in comparison with that of n