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Enantioselective Copper-Catalyzed Carboetherification of Unactivated Alkenes

✍ Scribed by Bovino, Michael T.; Liwosz, Timothy W.; Kendel, Nicole E.; Miller, Yan; Tyminska, Nina; Zurek, Eva; Chemler, Sherry R.

Book ID: 121848305
Publisher: John Wiley and Sons
Year: 2014
Tongue: English
Weight: 715 KB
Volume: 53
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201402462

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## Abstract It was shown that dichloramine‐T (**1**) reacted with cyclohexene in acetonitrile to give __N__^1^‐(2‐chlorocyclohexyl) amidine **2a** and __N__‐(2‐chlorocyclohexyl)acetamide (**3**) __via__ the competitive addition of acetonitrile and __N__‐chloro‐__N__‐tosylamino anion to cyclohexenec