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Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes

✍ Scribed by Zhu, Rong; Buchwald, Stephen L.


Book ID
111938488
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
589 KB
Volume
134
Category
Article
ISSN
0002-7863

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## Abstract It was shown that dichloramine‐T (**1**) reacted with cyclohexene in acetonitrile to give __N__^1^‐(2‐chlorocyclohexyl) amidine **2a** and __N__‐(2‐chlorocyclohexyl)acetamide (**3**) __via__ the competitive addition of acetonitrile and __N__‐chloro‐__N__‐tosylamino anion to cyclohexenec