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Enantioselective Conjugate Addition of Oximes to Trisubstituted β-Nitroacrylates: An Organocatalytic Approach to β 2,2 -Amino Acid Derivatives

✍ Scribed by Zhang, Fu-Gen; Yang, Qing-Qing; Xuan, Jun; Lu, Hai-Hua; Duan, Shu-Wen; Chen, Jia-Rong; Xiao, Wen-Jing

Book ID
118030857
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
688 KB
Volume
12
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Enantioselective Co
ChemInform Abstract: Enantioselective Conjugate Addition of Oximes to Trisubstituted β-Nitroacrylates: An Organocatalytic Approach to β2,2-Amino Acid Derivatives.
✍ Fu-Gen Zhang; Qing-Qing Yang; Jun Xuan; Hai-Hua Lu; Shu-Wen Duan; Jia-Rong Chen; 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 53 KB 👁 1 views

## Abstract The configuration of the olefins has significant influence on the stereoselectivity: the (Z)‐isomer provides the highest yield and enantioselectivity, while the (E)‐isomer or the Z/E‐mixture afford poor results.