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Enantioselective aza-Henry Reaction Using Cinchona Organocatalysts.

✍ Scribed by Luca Bernardi; Francesco Fini; Raquel P. Herrera; Alfredo Ricci; Valentina Sgarzani

Publisher
John Wiley and Sons
Year
2006
Weight
29 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Enantioselective Aza-Henry Reaction with Acyclic Guanidine-Thiourea Bifunctional Organocatalyst
✍ Keisuke Takada; Kazuo Nagasawa 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB 👁 2 views

## Abstract magnified image A highly enantioselective aza‐Henry reaction of imines with nitromethane was achieved with a reactive guanidine‐thiourea bifunctional organocatalyst affording β‐nitroamines with high enantioselectivity (up to 96% __ee__). The diastereo‐ and enantioselective version of t