## Abstract magnified image A highly enantioselective aza‐Henry reaction of imines with nitromethane was achieved with a reactive guanidine‐thiourea bifunctional organocatalyst affording β‐nitroamines with high enantioselectivity (up to 96% __ee__). The diastereo‐ and enantioselective version of t
Enantioselective Aza-Henry Reaction Catalyzed by a Bifunctional Organocatalyst.
✍ Scribed by Tomotaka Okino; Satoru Nakamura; Tomihiro Furukawa; Yoshiji Takemoto
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 125 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
📜 SIMILAR VOLUMES
## Abstract Bifunctional thiourea **1 a** catalyzes aza‐Henry reaction of nitroalkanes with __N__‐Boc‐imines to give __syn__‐β‐nitroamines with good to high diastereo‐ and enantioselectivity. Apart from the catalyst, the reaction requires no additional reagents such as a Lewis acid or a Lewis base.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.