## Abstract For Abstract see ChemInform Abstract in Full Text.
Enantioselective Aza-Henry Reaction Catalyzed by a Bifunctional Organocatalyst
✍ Scribed by Okino, Tomotaka; Nakamura, Satoru; Furukawa, Tomihiro; Takemoto, Yoshiji
- Book ID
- 115465177
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 52 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
## Abstract magnified image A highly enantioselective aza‐Henry reaction of imines with nitromethane was achieved with a reactive guanidine‐thiourea bifunctional organocatalyst affording β‐nitroamines with high enantioselectivity (up to 96% __ee__). The diastereo‐ and enantioselective version of t
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract Bifunctional thiourea **1 a** catalyzes aza‐Henry reaction of nitroalkanes with __N__‐Boc‐imines to give __syn__‐β‐nitroamines with good to high diastereo‐ and enantioselectivity. Apart from the catalyst, the reaction requires no additional reagents such as a Lewis acid or a Lewis base.