for their generous supply of ligands 24 and 10, 14, and 15, respectively. We are indebted to Corrado Sangermani and Gloria Borin for their synthetic expertise and contributions. Special thanks go to Maurizio Franzini for his advice. This work was supported by the University of Pavia (Progetto Giovan
Enantioselective Allylation of Carbonyl Compounds with Titanium-Carbohydrate Complexes
β Scribed by Dr. Martin Riediker; Dr. Rudolf O. Duthaler
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 266 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0044-8249
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The compound Cp\*Ti[Ξ· 6 -C 5 H 4 C(H)(tBu)]Cl (1) reacts with ketones, aldehydes, and esters to give Ο,Ο-chelate complexes with Cp~O ligands through insertion of the carbonyl group into the Ti-C(H)(tBu) bond. Starting from diastereomerically pure 1, the reaction with symmetric ketones R 2 CO led to