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Enantioselective Allylation of Aldehydes Catalyzed by Diastereoisomeric Bis(tetrahydroisoquinoline) N,N′-Dioxides

✍ Scribed by Klára Vlašaná; Radim Hrdina; Irena Valterová; Martin Kotora

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
183 KB
Volume
2010
Category
Article
ISSN
1434-193X

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## Abstract magnified image Unsymmetrically 3,3′‐substituted axially chiral bis(tetrahydroisoquinoline) __N,N′‐__dioxides can be prepared in just three steps. They exhibit unique catalytic activity (turnover frequency, enantioselectivity, substrate scope) in the asymmetric allylation of aromatic a