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ChemInform Abstract: Enantioselective Allylation of Aldehydes Catalyzed by Diastereoisomeric Bis(tetrahydroisoquinoline) N,N′-Dioxides.

✍ Scribed by Klara Vlasana; Radim Hrdina; Irena Valterova; Martin Kotora

Publisher
John Wiley and Sons
Year
2011
Weight
58 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Asymmetric allylation of aromatic (I) and α,β‐unsaturated aldehydes (IV) with allyltrichlorosilane (II) proceeds smoothly in THF in the presence of (S~ax~)‐bis(tetrahydroisoquinoline N‐oxide) to give the products (III) and (V) in good yields and moderate to high enantioselectivity.

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