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Enantioselective addition of terminal alkynes to N-(diphenylphosphinoyl)imines catalyzed by Zn–BINOL complexes

✍ Scribed by Gonzalo Blay; Eric Ceballos; Alicia Monleón; José R. Pedro


Book ID
113929272
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
272 KB
Volume
68
Category
Article
ISSN
0040-4020

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Enantioselective Addition of Organozinc
✍ Manabu Hatano; Takashi Miyamoto; Kazuaki Ishihara 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 265 KB 👁 1 views

## Abstract The enantioselective addition of organozinc reagents to aromatic and aliphatic aldehydes **1** gives secondary alcohols **2** with excellent enantioselectivities in high yields through the catalytic use of (__R__)‐3,3′‐bis(diphenylphosphinoyl)‐BINOL (**3**) or (__R__)‐3,3′‐bis(diphenylt