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Enantioselective Addition of Diethylzinc to Aromatic Aldehydes Catalyzed by New Chiral Oxazolidine Ligand.

✍ Scribed by Yong-feng Kang; Lei Liu; Rui Wang; Ming Ni; Zhi-jian Han

Publisher
John Wiley and Sons
Year
2005
Weight
16 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract Enantioselective addition of diethylzinc to a series of aromatic aldehydes was developed using a modular amino acid amide chiral ligand (2__S__)‐3‐phenyl‐__N__‐((__R__)‐1‐phenyl‐ethyl)‐2‐(tosylamino)propanamide without using titanium complex. The catalytic system employing 10 mol% of 1g