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Enantioselective addition of alkenylzinc reagents to aldehydes with organoboronates as the alkenyl source

โœ Scribed by Zhuo Chai; Xin-Yuan Liu; Jun-Kang Zhang; Gang Zhao


Book ID
108284191
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
162 KB
Volume
18
Category
Article
ISSN
0957-4166

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A mechanistic model for the enantioselective addition of diethylzinc to benzaldehyde with chiral tridentate lithium complexes as catalysts correctly predicts the observed direction of enantioselectivity which occurs at levels of 8595% ee. A recent paper from these laboratories described two rationa