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Enantiomerization trends in 1,8-bis(trimethylelement)naphthalenes

✍ Scribed by Hounshell, W. Douglas; Anet, Frank A. L.; Cozzi, Franco; Damewood, James R.; Johnson, Constance A.; Sjoestrand, Ulf; Mislow, Kurt


Book ID
121360977
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
306 KB
Volume
102
Category
Article
ISSN
0002-7863

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A series of 1,8-bis(phosphino)naphthalenes 2 was prepared by treating 1,8-dilithionaphthalene with the appropriate chloro-or bromophosphines RRЈPX; R, RЈ ‫ס‬ Me (for 2a), iPr (for 2c), Cy (for 2d), Ph (for 2f); R ‫ס‬ tBu, RЈ ‫ס‬ Ph (for 2e) (X ‫ס‬ Cl) and R, RЈ ‫ס‬ Et; X ‫ס‬ Br (for 2b). The resulti