Enantiomerically Pure α-Substituted Cyanohydrins Derived from Benzaldehyde
✍ Scribed by Jose L. Garcia Ruano; Ana M. Martin Castro; Francisco Tato; Diego J. Cardenas
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 9 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
We have reported' the transformation of 2,3-unsaturated glycosides 1 into the respective 2,3-dideoxyhex-2-enono-1 ,Slactones 2 by oxidation with 30% hydrogen peroxide in the presence of molybdenum trioxide as catalyst, followed by dehydration of the resulting hydroperoxide 3. Other syntheses of 2 ha
## Abstract For Abstract see ChemInform Abstract in Full Text.
The synthesis of a large variety of enantiomerically pure substituted reactive cyclopentenes **16, 23, 24** and **28** have been synthesized from the readily available (−)‐quinic acid **1**. The straightforward strategy involves a high‐yielding intramolecular aldolization‐dehydration of acyclic 1,6‐