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Enantiomerically pure compounds related to chiral hydroxy acids derived from renewable resources

✍ Scribed by Haleema, Simimole; Sasi, Paleapadam Vavan; Ibnusaud, Ibrahim; Polavarapu, Prasad L.; Kagan, Henri B.


Book ID
111913676
Publisher
The Royal Society of Chemistry
Year
2012
Tongue
English
Weight
739 KB
Volume
2
Category
Article
ISSN
2046-2069

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1,3-Dioxanone Derivatives from Ξ²-Hydroxy
✍ Dieter Seebach; JΓΌrg Zimmermann πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 German βš– 346 KB

9.VI. 86) (R)-3-Hydroxybutyric acid (from the biopolymer PHB) and pivalaldehyde give the crystalline cis-or (R, R)-2-(tert-butyl)-6-methy1-1,3-dioxan-4-one (la), the enolate of which is stable at low temperature in THF solution and can be alkylated diastereoselectively (-3, 4, 5, and 7). Phenylselen