ChemInform Abstract: Enantiomerically Pure Compounds Related to Chiral Hydroxy Acids Derived from Renewable Resources
β Scribed by Haleema, Simimole; Sasi, Paleapadam Vavan; Ibnusaud, Ibrahim; Polavarapu, Prasad L.; Kagan, Henri B.
- Book ID
- 118756782
- Publisher
- John Wiley and Sons
- Year
- 2013
- Weight
- 18 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0931-7597
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9.VI. 86) (R)-3-Hydroxybutyric acid (from the biopolymer PHB) and pivalaldehyde give the crystalline cis-or (R, R)-2-(tert-butyl)-6-methy1-1,3-dioxan-4-one (la), the enolate of which is stable at low temperature in THF solution and can be alkylated diastereoselectively (-3, 4, 5, and 7). Phenylselen