Enantiomeric excess determination of some chiral sulfoxides by NMR: use of (S)-Ibuprofen® and (S)-Naproxen® as shift reagents
✍ Scribed by Laëtitia Fauconnot; Caroline Nugier-Chauvin; Nicolas Noiret; Henri Patin
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 194 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Primary 1-deuterlo alcohols, RCHDOH, which are chiral have great value in the study of mechanisms of chemical merically pure alcohols of this type have been obtained various chemical asymmetric reactions have been used to by virtue of deuterium substitution, and biochemical reactions. 2.3 Enantioinv
## Abstract The chiral phosphorus derivatizing agent (CDA) 1 was prepared from optically pure (S)‐__1,1‐bis‐2‐naphthol__. It was first used in the determination of the enantiomeric excess of chiral alcohols and amines by means of ^31^P NMR spectroscopy. It showed that, for the chiral aromatic alcoh
## Abstract The use of P(III) and P(V) organophosphorus derivatizing agents prepared from __C__~2~ symmetrical (1__R__,2__R__)‐ and (1__S__,2__S__)‐__trans__‐__N__,__N__′‐bis‐[(__S__)‐α‐phenylethyl]‐cyclohexane‐1,2‐diamines **1** and **2**, as well as (1__R__,2__R__)‐ and (1__S__,2__S__)‐__trans__‐