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Enantiodivergent synthesis of (−)-methylenolactocin and (+)-methylenolactocin from d-mannitol

✍ Scribed by Manju Ghosh; Sritama Bose; Soumitra Maity; Subrata Ghosh

Book ID: 104097049
Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 204 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.10.011

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✦ Synopsis

An enantiodivergent synthesis of both enantiomers of methylenolactocin is described through stereocontrolled addition of n-pentyl magnesium bromide to two D-mannitol-derived diastereomerically related aldehydes having an a-chiral center with a b hetero atom.

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