Emulsion copolymerization of styrene and sodium acrylate
✍ Scribed by S. Nuño-Donlucas; A. I. Rhoton; S. Corona-Galvan; J. E. Puig; E. W. Kaler
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 410 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0170-0839
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The emulsion copolymerization of styrene and sodium acrylate is reported using either a water-soluble initiator (potassium persulfate, or KPS), or an oil-soluble one [2,2-azoisobutyronitrile (AIBN)]. Reaction rates are fast with both KPS and AIBN. With KPS, conversions ú90% are achieved in 50 min, w
Polymerizable styrenic surfactants (surfmers) and nonreactive analogs, have been applied in emulsion copolymerization of acrylic monomers in a seeded semibatch process. Stable core-shell latexes with low levels of coagulum and controlled particle size have been obtained; some of them, with either st