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Emulsion copolymerization of styrene and sodium acrylate

✍ Scribed by S. Nuño-Donlucas; A. I. Rhoton; S. Corona-Galvan; J. E. Puig; E. W. Kaler


Publisher
Springer
Year
1993
Tongue
English
Weight
410 KB
Volume
30
Category
Article
ISSN
0170-0839

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The emulsion copolymerization of styrene and sodium acrylate is reported using either a water-soluble initiator (potassium persulfate, or KPS), or an oil-soluble one [2,2-azoisobutyronitrile (AIBN)]. Reaction rates are fast with both KPS and AIBN. With KPS, conversions ú90% are achieved in 50 min, w

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Polymerizable styrenic surfactants (surfmers) and nonreactive analogs, have been applied in emulsion copolymerization of acrylic monomers in a seeded semibatch process. Stable core-shell latexes with low levels of coagulum and controlled particle size have been obtained; some of them, with either st