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Emission Mössbauer spectroscopic studies on mixed-valence states of57Fe atoms produced in57Co-labeled trinuclear cobalt-iron carboxylates

✍ Scribed by T. Sato; M. Katada; K. Endo; M. Nakada; H. Sano


Book ID
112693509
Publisher
Springer
Year
1993
Tongue
English
Weight
746 KB
Volume
173
Category
Article
ISSN
1588-2780

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Mössbauer spectroscopic studies of the e
✍ Hirotoshi Sano; Toshiaki Ohnuma 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 245 KB

57Fe-MSssbauer emission spectra of 57Co-labelled [Co(NH&] 2(C204)3-4H,O and [Co&&] ,(C,O,),-9H,O show an increased yield of 57Fe(Il) species. The stabilization of ferrous 57Fe species is attributed to the consequences of an autoradiolytic process involving oxdate anions in the se&d coordination sphe