𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Emission and energy transfer of triplet difluoromethylene produced in the reaction of oxygen atoms with tetrafluoroethylene

✍ Scribed by Seiichiro Koda


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
344 KB
Volume
55
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


Structured emΓ―ssion spectra have been observed in tbe wavelengtb range 470-720 & from the reaction of oxygen atoms wΓ―tb tetrafluoroetbylene. The emΓ―ssion is tentatively assigned to the CF2eBI) + CFz(t At) phosphorescence tiansition. The excited singlet CFz('Bt) is also formed through the triplet-Mp:et annΓ―hΓ―Γ―tion from the triplet CF2.


πŸ“œ SIMILAR VOLUMES


N2+(Bβ€”X) Emission produced from the ther
✍ Hiroshi Obase; Masaharu Tsuji; Yukio Nishimura πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 250 KB

\(\mathrm{N}_{2}^{+}\left(\mathrm{B}^{2} \Sigma_{\mathrm{u}}^{+}-\mathrm{X}^{2} \Sigma_{\mathrm{g}}^{+}\right)\)emission was observed from the near-resonant charge transfer between \(\mathrm{Ne}_{2}^{+}\)and \(\mathrm{N}_{2}\). Vibrational populations for \(v^{\prime}=0\) and 1 of \(N_{2}^{+}(B)\) w

Common intermediates in the transfer of
✍ S.M. Japar; M. Pomerantz; E.W. Abrahamson πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 English βš– 285 KB

## Irradiation of acetone-d6 and tetrnmethyl-ethylene (ThlE) yields acelone and T?AE-d6 as the only products. The comparable behavior of this reaction and the transfer of triplet excitation energy from aGetone to olefins points to a common molecular triplet oxetane intermediate for both processes.

Solvent dependence of triplet energy tra
✍ Minoru Yamaji; Takuya Tanaka; Haruo Shizuka πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 420 KB

It is found that the triplet-triplet energy transfer (ET) reaction between triplet benzophenone ('BP\*) and l-naphthol (ROH) is competitive with the hydrogen atom abstraction (HA) reaction. The rate constant of ET is enhanced with an increase of solvent polarity while that of HA is reduced. A possib

Approximately projected UHF MΓΈller-Pless
✍ Takayuki Fueno; Yoichi Takahara; Kizashi Yamaguchi πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 550 KB

Geometries for the CH2CH,0 diradical, both singlet and triplet, in various conformations were optimized and the unimolecular reaction paths for the lowest-lying singlet and triplet diradicals were determined by the SCF energy gradient method employing the 6-31G\* basis functions. Approximately proje