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Common intermediates in the transfer of triplet excitation energy and molecular exchange reactions

✍ Scribed by S.M. Japar; M. Pomerantz; E.W. Abrahamson

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
285 KB
Volume
2
Category
Article
ISSN
0009-2614

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✦ Synopsis

Irradiation

of acetone-d6 and tetrnmethyl-ethylene (ThlE) yields acelone and T?AE-d6 as the only products. The comparable behavior of this reaction and the transfer of triplet excitation energy from aGetone to olefins points to a common molecular triplet oxetane intermediate for both processes.

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