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Elucidation of the conformations and absolute configurations of enantiomerically pure tetralin derivatives

✍ Scribed by Gábor Tóth; András Simon; Torsten Linker; Frank Rebien; Jürgen Kraus; Gerhard Bringmann


Book ID
101251730
Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
184 KB
Volume
37
Category
Article
ISSN
0749-1581

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✦ Synopsis


The enantioselective epoxidation of 1,2-dihydronaphthalenes (2) a †orded optically active tetralin derivatives (3 and 4). The relative conÐgurations and conformational behavior of all products were elucidated by detailed one-and two-dimensional 1H and 13C NMR methods. The last required stereochemical information, the absolute conÐguration of 4, attained through comparison of experimental and calculated CD spectra.


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