## Abstract Recent results on surface reaction steps in the oxidative coupling of methane (OCM) obtained from (1) transient experiments and (2) a microkinetic analysis are summarized. The interaction of methane and oxygen with MgO and Sm~2~O~3~ surfaces was investigated by applying H/Dβ and oxygenβ
β¦ LIBER β¦
Elementary steps of radical-surface interactions in oxidative coupling of methane
β Scribed by M.Yu. Sinev
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 202 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0920-5861
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On pulsing over MgO containing various amounts of praseodym-CH 4 ium oxide at 1023 K, the conversion decreased with increasing pulse (PrO x ) C H 4 number, and both the initial activity and selectivity to products C 2 (corresponding to the Γrst pulse) decreased with increasing content. Char-PrO x ac