Elemental fluorine as a legitimate reagent for selective fluorination of organic compounds
β Scribed by Rozen, Shlomo
- Book ID
- 120280702
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 830 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0001-4842
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π SIMILAR VOLUMES
Methyl gfycopyranosides reacted with dicthylamin~sulfur trifluoride (DAST) in the absence of solvent to yield methyl dideoxy-difluoro and deoxy-fluoro glycopyranosides. Methyl n-D-glycopyranosides produced 6-deoxy-6-fluoro-and 4,6-dideoxy-4,6-ditluoro derivatives with Walden inversion at C-4. Methyl
## Abstract 2βHydroperfluoropropyl azide CF~3~CHFCF~2~N~3~, 1, an inexpensive, readily available, and stable (easy to store) compound, is suggested as an effective fluorinating reagent for different classes of trivalent organophosphorus compounds in accordance with the general scheme R~3~P β R~3~PF