Electrolytic partial fluorination of organic compounds. Part 16. Selective indirect anodic fluorination of dithioacetals using a bromine mediator
β Scribed by Toshio Fuchigami; Masaru Sano
- Publisher
- Elsevier
- Year
- 1996
- Tongue
- English
- Weight
- 375 KB
- Volume
- 414
- Category
- Article
- ISSN
- 1572-6657
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Anodic fluorination of 2-cyano-1-methylpyrrole using Et 3 Nβ’2HF in an undivided cell provided the corresponding 5-fluoropyrrole and 2,5,5-trifluoro-1-methyl-3-pyrrolin-2-carbonitrile while the use of Et 3 Nβ’3HF afforded selectively the latter product, which was readily hydrolyzed to isolable 5,5-dif