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Electrostatic solvent effect on the circular dichroism of the carbonyl n→π* transition.

✍ Scribed by M.F. Ruiz-Lopez; D. Rinaldi

Book ID
119115931
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
181 KB
Volume
93
Category
Article
ISSN
0166-1280

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Calculations of the circular dichroism o
Calculations of the circular dichroism of double-helical nucleic acids. II. Effects involving n → π* transitions
✍ David S. Studdert; Robert C. Davis 📂 Article 📅 1974 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 725 KB

## Abstract The circular dichroism of double‐helical nucleic acids was calculated as a function of geometry, including terms involving __n__ → π\* transitions. The “nonbonding” __n__ or σ orbitals were of the azine type, delocalized, but concentrated at the nitrogen atoms of the purines and pyrimid

Calculations of the circular dichroism o
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✍ David S. Studdert; Robert C. Davis 📂 Article 📅 1974 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 657 KB

## Abstract The circular dichroism of double‐helical nucleic acids was calculated as a function of geometry using the theory of Tinoco and Johnson. This theory does not include contributions of near ultraviolet transitions that are not π → π\* in nature. The calculated circular dichroism shows a st