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Electropolymerized Cr–salen complexes for the heterogeneous asymmetric hetero Diels-Alder reaction

✍ Scribed by Mohamed Mellah; Benoît Ansel; Frédéric Patureau; Arnaud Voituriez; Emmanuelle Schulz

Publisher: Elsevier Science
Year: 2007
Tongue: English
Weight: 269 KB
Volume: 272
Category: Article
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2007.03.013

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✦ Synopsis

New electropolymerized chiral salen-chromium complexes have been successfully used as heterogeneous catalysts for the asymmetric hetero Diels-Alder reaction. These insoluble catalysts were reused up to six times affording the expected products with unchanged enantioselectivity along the recycling procedure. Promising attempts to use these catalysts in a multi-substrate procedure are described.

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