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Electrophilic hydrogen substitution reactions in η5-indenyl and η5-fluorenyltricarbonyl complexes of manganese and rhenium

✍ Scribed by I. A. Lobanova; V. I. Zdanovich; P. V. Petrovskii; N. I. Vasyukova; N. E. Kolobova

Book ID
112446567
Publisher
Springer
Year
1987
Tongue
English
Weight
514 KB
Volume
36
Category
Article
ISSN
1573-9171

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Addition of a nucleophile to an (η 6 -arene)tricarbonylchromium or a tricarbonyl(η 5 -cyclohexadienyl)manganese complex substituted with a leaving group X (X = F, Cl, OMe, OPh, NR 2 ) affords (after treatment with acid) new complexes with the same η 6 or η 5 hapticity. The overall reaction involves