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Electrophilic cyclization of regular α-monoterpenols catalyzed by BF3etherate

✍ Scribed by V. A. Dragan; V. V. Veselovskii; A. M. Moiseenkov

Book ID
112449802
Publisher
Springer
Year
1990
Tongue
English
Weight
55 KB
Volume
39
Category
Article
ISSN
1573-9171

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Cationic cyclization of regular α-monote
Cationic cyclization of regular α-monoterpenols as a model for tri- and tetracyclic diterpene biosynthesis
✍ V.V Veselovsky; V.A Dragan; A.M Moiseenkov 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 211 KB

Low-temperature boron trifluoride etherate initiated cyclization of o(-geraniol, d-nerol, and d-linalool leads to regioisomeric dimethylvinylcyclohexenes possessing a rare monoterpene carbon skeleton along with bicyclou.2.1]octyl fluoride. The cyclization mimics biosynthesis of tri-and tetracyclic d