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Electrophilic Cleavage of One Silicon—Carbon Bond of Pentacoordinate Tetraorganosilanes: Synthesis of Silalactones.

✍ Scribed by Mitsuru Shindo; Kenji Matsumoto; Kozo Shishido

Book ID
101955306
Publisher
John Wiley and Sons
Year
2004
Weight
157 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

📜 SIMILAR VOLUMES

Cleavage of silicon-vinyl carbon bond by
Cleavage of silicon-vinyl carbon bond by nBu4NF
✍ Hiroji Oda; Mitsuyoshi Sato; Yoshitomi Morizawa; Koichiro Oshima; Hitosi Nozaki 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 228 KB

DimethyZphenyZsiZyZ-and diphenyZmethyZsiZyZ-vinyl carbon bonds are cleaved with ni3uqNF. DesiZyZation of I-phenyZthio-l-trimethyZsiZyZ-lalkenes in the presence of aldehyde moiety gives carbanion adducts. The affinity of fluoride ion for silicon has been well recognized and widely used for the cleava