𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Electrophilic Cleavage of One Silicon–Carbon Bond of Pentacoordinate Tetraorganosilanes: Synthesis of Silalactones

✍ Scribed by Mitsuru Shindo; Kenji Matsumoto; Kozo Shishido


Book ID
101559854
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
108 KB
Volume
43
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Cleavage of silicon-vinyl carbon bond by
✍ Hiroji Oda; Mitsuyoshi Sato; Yoshitomi Morizawa; Koichiro Oshima; Hitosi Nozaki 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 228 KB

DimethyZphenyZsiZyZ-and diphenyZmethyZsiZyZ-vinyl carbon bonds are cleaved with ni3uqNF. DesiZyZation of I-phenyZthio-l-trimethyZsiZyZ-lalkenes in the presence of aldehyde moiety gives carbanion adducts. The affinity of fluoride ion for silicon has been well recognized and widely used for the cleava