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Electrophilic additions to dienes. III. Hydrochlorination of phenylallene and its derivatives

โœ Scribed by Okuyama, Tadashi.; Izawa, Kunisuke.; Fueno, Takayuki.


Book ID
120749953
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
483 KB
Volume
95
Category
Article
ISSN
0002-7863

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The regioselectivity of electrophilic additions can be controlled by carboxylate or dialkoxymethyl Under kinetic control, enones 1 add soft electrophiles, EX, to give the corresponding \_ adducts 2. --In contrast with 1, their synthetic precursors 3 were found to add EX with the opposite regioselect