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Electrooxidative Formation of 1,2-Diaroylcyclopropanes from 1,3-Diaroylpropanes in the Presence of KI.

โœ Scribed by Mitsuhiro Okimoto; Yukio Takahashi; Toyoji Kakuchi


Book ID
101939363
Publisher
John Wiley and Sons
Year
2003
Weight
84 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœ Charles W. Jefford; Danielle Jaggi; John Boukouvalas; Shigeo Kohmoto; Gรฉrald Ber ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 441 KB

## Abstract The dyeโ€sensitized photoโ€oxygenation of 1,3โ€dimethylindole in the presence of aldehydes initially generates a zwitterionic peroxide which condenses with the carbonyl function to give the corresponding __cis__โ€fused 1,2,4โ€trioxanes. Acetaldehyde gives a pair of diastereomers, one of whos