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Formation of 1-phenyl-2,3-dioxabicyclo[2.2.1]heptane in the reaction of 1,3-dibromo-4-phenylcyclopentane with hydrogen peroxide in the presence of silver trifluoroacetate

✍ Scribed by Takahashi, Kimio; Shiro, Motoo; Kishi, Morio


Book ID
118037391
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
978 KB
Volume
53
Category
Article
ISSN
0022-3263

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The Reaction of Singlet Oxygen with 1,3-
✍ Charles W. Jefford; Danielle Jaggi; John Boukouvalas; Shigeo Kohmoto; Gérald Ber 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 441 KB

## Abstract The dye‐sensitized photo‐oxygenation of 1,3‐dimethylindole in the presence of aldehydes initially generates a zwitterionic peroxide which condenses with the carbonyl function to give the corresponding __cis__‐fused 1,2,4‐trioxanes. Acetaldehyde gives a pair of diastereomers, one of whos