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Electronic transitions in chromium (III) complexes—III: Luminescence quantum yields and lifetimes

✍ Scribed by Keith DeArmond; Leslie S. Forster

Publisher
Elsevier Science
Year
1963
Weight
464 KB
Volume
19
Category
Article
ISSN
0371-1951

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Luminescence lifetimes and photoaquation quantum yields of RhAsX\* (A = NH3 or ND3, X-= Cl-or Br-) measured in aqueous solution indicate that emission and aquation are competitive processes of the same ligand field excited state. Lifetimes are lo-30 ns with the longer lived perdeuterio complexes als