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Electronic structures of octahedral cluster halides of transition metals [M6X8]n+, [M6X12]n+ and their interstitial compounds [M6X12Z]

✍ Scribed by Menghai Lin; Qianer Zhang

Book ID
113257465
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
612 KB
Volume
228
Category
Article
ISSN
0166-1280

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Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] Β΄n EtOH Β΄m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 Β΄6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The