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Electronic structure, stability, and reactivity of acyl peroxides

โœ Scribed by A. O. Litinskii; A. I. Shreibert; E. I. Shifrovich; L. -M. Z. Balyavichus; A. B. Bolotin


Book ID
112364917
Publisher
Springer
Year
1975
Tongue
English
Weight
241 KB
Volume
9
Category
Article
ISSN
0040-5760

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The reactivity of both the peroxide (2-tert-butylperoxy-2-methyl-5-hexene-3-yne) and hydroperoxide (2-hydroperoxy-2-methyl-5-hexene-3-yne) monomers in the radical copolymerization was compared. Using the Alfrey-Price Q and e scheme, Hammett correlations, and MNDO quantum-chemical model it was shown