Electronic structure of three-membered rings containing phosphorus atoms. PE spectroscopic investigations and model calculations

The electronic structure of phosphorus c

The electronic structure of phosphorus cages with the nortricyclane skeleton. – Model calculations and photoelectron spectroscopic investigations

✍ Gleiter, Rolf ;Böhm, Michael C. ;Eckert-Maksić, Mirjana ;Schäfer, Wolfgang ;Baud 📂 Article 📅 1983 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 440 KB 👁 1 views

The different reactivity of P,[Si(CH,),], (1) and P7(CH3), (2) is discussed in terms of a simple MO scheme. This scheme is based on semiempirical calculations (MIND0/3, MNDO) and on He(1) photoelectron spectroscopic investigations on 1 and 2. The electronic structure of similar cage compounds with t