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Electronic structure of the negative charge-transfer material Sr3FeMO7 (M=Fe, Co, Ni)

✍ Scribed by M. Abbate; H. Ascolani; L. Mogni; F. Prado; A. Caneiro


Book ID
103883406
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
198 KB
Volume
354
Category
Article
ISSN
0921-4526

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New spectroscopic absorption and luminescence data for the ions M(bpy)~ + @I = Fe, Ru, Os) provide the basis for a theoretical model of the electronic structure of these ions. An important aspect of the model is the essential localization of the triplet states, in contrast to the singlet states whic