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Electronic structure of octavalene. Photoelectron spectroscopic investigations

✍ Scribed by Gleiter, Rolf; Bischof, Peter; Christl, Manfred

Book ID
125981398
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
413 KB
Volume
51
Category
Article
ISSN
0022-3263

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The He@) photoelectron spectra of eight tazapentalenes, substituted in 1,3-position by electron releasing groups (dimethylamino, ethoxy, and tert-butyi) revealed that the first four ionization energies (6.4-9.3 eV) are due to ionziation from n MOs. This assignment is based on the comparison with the