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Electronic structure of [n.1.1]propellanes. PE (photoelectron) spectroscopic investigations

โœ Scribed by Gleiter, Rolf; Pfeifer, Karl Heinz; Szeimies, Guenter; Belzner, Johannes; Lehne, Klaus

Book ID
127165808
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
367 KB
Volume
55
Category
Article
ISSN
0022-3263

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The He@) photoelectron spectra of eight tazapentalenes, substituted in 1,3-position by electron releasing groups (dimethylamino, ethoxy, and tert-butyi) revealed that the first four ionization energies (6.4-9.3 eV) are due to ionziation from n MOs. This assignment is based on the comparison with the