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Electronic Structure of Non-Heme High-Valent Oxoiron Complexes with the Unprecedented [Fe2(μO)2]3+ Core

✍ Scribed by Dr. Abhik Ghosh; Prof. Dr. Jan Almlöf; Prof. Dr. Lawrence Que Jr.


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
423 KB
Volume
35
Category
Article
ISSN
0044-8249

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✦ Synopsis


This paper incorrectly proposed a mononuclear structure for I .

[4] Spectroscopic characterization of solid 2: ( B = 0.


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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.