The contributions to the electronic fact
β
P. Bertrand
π
Article
π
1987
π
Elsevier Science
π
English
β 488 KB
We present a new formulation of the various contributions to the electronic factor of bridge-assisted electron transfer rates, which explicitly takes into account the many-electron character of the wavefunctions and the overlap integrals between adjacent orbitals. Aside from superexchange terms, thi