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Electronic structure and reactivity of X2Co2(CO)6 (X2  RC2R′, P2, As2) and RxR′ 6-xC6Co2(CO)4 radical anions

✍ Scribed by R.S. Dickson; B.M. Peake; P.H. Rieger; B.H. Robinson; J. Simpson


Book ID
108354047
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
244 KB
Volume
172
Category
Article
ISSN
0022-328X

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✍ Domenico Osella; Luciano Milone; Carlo Nervi; Mauro Ravera 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 164 KB 👁 1 views

The electrochemical behaviour of the [Co 2 (CO) 6 ] 2 (µ-R-CϵC-through-space and through-bond interactions are operating with different relative weight depending on the spacer L. L-CϵC-R) and [Co 2 (CO) 4 (dppm)] 2 (µ-R-CϵC-L-CϵC-R) series is reported. Qualitative evidence suggests that both